Reinforced composite and method for recycling the same

ABSTRACT

The present invention relates to a reinforced composite and method for recycling the same. The reinforced composite comprises a reinforcement material in a cross-linked polymer matrix, wherein the cross-linked polymer comprises a cross-linking group derived from a curing agent represented by formula (I), Wherein R 1  is hydrogen, alkyl, cycloalkyl, heterocycloalkyl, alkenyl, cycloalkenyl, aryl, heteroaryl, alkoxy alkyl or alkynyl; A is alkyl, alkenyl, alkenene, alkylene-hetero-alkylene, alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene, 1,4-alkyl substituted piperazine, carbonyl, thiocarbonyl; B is alkyl, alkenyl, alkenene, alkylene-hetero-alkylene, alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene, 1,4-alkyl substituted piperazine, carbonyl, thiocarbonyl; R 2  is hydrogen, alkyl, aminoalkyl, alkyl-amino-alkyl, cycloalkyl, heterocycloalkyl, alkenyl, aryl, or heteroaryl; and R 3  is hydrogen, alkyl, aminoalkyl, alkyl-amino-alkyl, cycloalkyl, heterocycloalkyl, alkenyl, aryl, or heteroaryl.

CROSS-REFERENCE TO RELATED PATENT APPLICATIONS

This application claims priority to and benefit of PCT/CN2011/076980,filed on Jul. 8, 2011, the contents of which are incorporated herein byreference in their entireties.

TECHNOLOGY FIELD

The invention belongs to the field of composite materials and epoxycompositions. More specifically the present invention belongs in thefield of recyclable composite materials and in the field ofreworkable/degradable epoxies.

BACKGROUND OF THE INVENTION

Epoxies serve massive global markets in adhesives and coatings, and arealso one of the industry standard thermosetting plastic matrices usedfor construction of fiber reinforced plastics (FRP). FRPs are compositematerials consisting of a polymer matrix and a fiber such as carbonfiber, fiberglass, aramid fiber, natural fiber, or other fiber. Thefiber serves to enhance the properties of the plastic in areas such asstrength and elasticity. FRPs are also commonly referred to as “plasticcomposites” or, for simplicity, just “composites.” The term “plasticcomposites” can also embody plastic materials that have non-fibrousentities incorporated in them such as metals or nanomaterials. Plasticcomposites provide lightweight alternatives to other structuralmaterials (e.g., steel or aluminum) and are widely used in theautomotive, aerospace, nautical craft, wind energy, and sporting goodssectors. The incorporation of lightweight composites can offersubstantial environmental benefits by way of leading to increased energyefficiency; yet, the positive impact of thermosetting plastic compositesis offset by their lack of recyclability and persistence in theenvironment. The predicted waste accumulation in the growing wind powerindustry is an illustrious example. The current output of wind energy isapproximately 10 times that of the production in 1980, and windmillblade propellers can reach over 60 meters in length. The materialwastage from wind motor blade is estimated to reach 225,000 tons peryear by 2034. The weight percentage of epoxy in fiber reinforced epoxiestypically is in the range of 25-40%. The raw materials (i.e. the plasticand fiber) that go into composite construction can be expensive, and areusually of petrochemical origins. Thus, there are both economic andenvironmental drivers for the development of new recyclable fiberreinforced epoxy plastics.

The most common epoxy formulations consist of a diepoxide (“resin”) anda polyamine (“hardener”) to form a cross-linked polymeric network ofessentially infinite molecular weight (the combination of“resin+hardener” is sometimes referred to as “cured epoxy” or “curedresin” or simply “resin” or epoxy). The widespread utility of such epoxyformulations for composite manufacturing is due to excellentprocessability prior to curing and their excellent post-cure adhesion,mechanical strength, thermal profile, electronic properties, chemicalresistance, etc. Further, the high-density, three-dimensional network ofepoxies makes them extremely robust materials, tolerant of a wide rangeof environmental conditions. At the same time, the cross-linked networkmakes their removal, recycling and reworkability notoriously difficult.The cross-linking reactions that occur with conventionally usedpolyamine epoxies formulation are essentially irreversible; therefore,the material cannot be re-melted and re-shaped without decomposition;the material cannot be readily dissolved either. As a result, fiberreinforced epoxies or epoxy-based composite materials are not amenableto standard recycling practices because the epoxy matrix and fiberscannot be readily separated, and recovered.

Current disposal methods of composites typically involve land filling,grinding and burning. Burning provides a mechanism to recover some ofthe energy input, but the incineration process requires large amounts ofenergy and remains questionable from an environmental standpoint. Anemerging technology for recycling of carbon fiber composites involvesspecial incinerators that are capable of burning away the plastic matrixof the composite and leaving behind the carbon fiber, which then can bereclaimed. While this approach is a step forward with regard tosustainability, it does not represent a more fully recyclable approachas the plastic matrix is not recovered in a repurposable form as it isdestroyed in the process.

There are no known examples in the prior art of use of compositematerials constructed from reworkable epoxy compositions. The use ofreworkable and/or degradable epoxy resin composition for the fabricationof composite materials is unknown in the art. Further, the recycling ofdegradable epoxy composites, whereby the constitution of the epoxy andthe reinforcement material are recovered with high efficiency.

SUMMARY OF THE INVENTION

The present invention relates to a reinforced composite comprising areinforcement material in a cross-linked polymer matrix (preferably across-linked epoxy resin matrix), wherein the cross-linked polymercomprises a cross-linking group derived from a curing agent representedby formula I:

wherein R¹ is hydrogen, alkyl, cycloalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, aryl, heteroaryl, alkoxy alkyl or alkynyl; A is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, thiocarbonyl; B is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, thiocarbonyl; R² ishydrogen, alkyl, aminoalkyl, alkyl-amino-alkyl, cycloalkyl,heterocycloalkyl, alkenyl, aryl, or heteroaryl; and R³ is hydrogen,alkyl, aminoalkyl, alkyl-amino-alkyl, cycloalkyl, heterocycloalkyl,alkenyl, aryl, or heteroaryl.

In the reinforced composite of the present invention, the cross-linkedepoxy resin matrix is derived from a degradable curing agent, an epoxyresin and an optional auxiliary material, said curing agent isrepresented by the following formula I:

wherein R¹ is hydrogen, alkyl, cycloalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, aryl, heteroaryl, alkoxy alkyl or alkynyl; A is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, thiocarbonyl; B is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, thiocarbonyl; R² ishydrogen, alkyl, aminoalkyl, alkyl-amino-alkyl, cycloalkyl,heterocycloalkyl, alkenyl, aryl, or heteroaryl; and R³ is hydrogen,alkyl, aminoalkyl, alkyl-amino-alkyl, cycloalkyl, heterocycloalkyl,alkenyl, aryl, or heteroaryl.

The present invention further relates to a method for recycling thereinforced composite, comprising a step of degrading the cross-linkedpolymer matrix using an acid and a solvent, preferably under a heatingcondition (for example, heating at a temperature of 15-400° C.,preferably 80-120° C., for 1-24 hours, preferably 4-8 hours).

The acid used in the present invention is at least one selected from agroup consisting of hydrochloric acid, acetic acid, lactic acid, formicacid, propionic acid, citric acid, methane sulfonic acid, p-toluenesulfonic acid, nitric acid, sulfuric acid, benzoic acid, and phthalicacid, at a concentration range of 2-90% by weight, preferably 10-20% byweight.

The solvent used in the present invention is at least one selected froma group consisting of methanol, ethanol, ethylene glycol, isopropylalcohol, butyl alcohol, pentanol, hexanol, heptanol, octanol alcohol,nonyl alcohol, and water.

It is preferable that the method for recycling the reinforced compositeof the present invention further comprises a step of recovering thedegradation product via a filtration process and/or a precipitationprocess.

According to the present invention, a fully recyclable fiber reinforcedcomposite can be obtain, as a cross-linked epoxy resin matrix derivedfrom a degradable curing agent and an epoxy resin is used. Moreover, therecycling method of the fiber reinforced composite can be performedunder relatively mild reaction conditions, economically, and easy tocontrol.

DESCRIPTION OF THE DRAWINGS

FIG. 1 shows the recovered epoxy polymer and recovered carbon fiberafter recycling of the degradable composite as described in example 12.

FIG. 2 shows the recovered carbon fiber after recycling of thedegradable composite as described in example 13.

FIG. 3 shows the properties of non-composites as described in example14.

PREFERABLE EMBODIMENTS OF THE INVENTION

The present invention relates to the fabrication of recyclable fiberreinforced epoxy resin composites. More specifically, the presentinvention relates to the use of epoxy resin compositions derived fromdiepoxide resins with reworkable amine hardeners for the fabrication,construction, and/or manufacturing of recyclable fiber reinforced epoxycomposites. Such recyclable thermosetting composite materials can befabricated using standard composite manufacturing techniques such as wetlay-up, filament winding, vacuum infusion, compression molding, etc.These materials have excellent mechanical properties that make themuseful for different composite applications. These composites materialscan also be degraded under specific conditions, leading to theseparation and recovery of both the reinforcing fiber and the epoxyresin constitution in the form of an epoxy polymeric material. Thesecomposite materials can be recycled precisely because the epoxy matrixof a fabricated composite is derived from reworkable epoxy compositions.Thus, the present invention enables the manufacture of recyclable epoxycomposites as both the epoxy, and the components in contact with theepoxy, can be readily separated and recovered using a solution-basedrecycling process.

The present invention employs diepoxide resins that are hardened withdegradable curing agents, which are combined with the fibers to preparefiber reinforced epoxy resin composites. The fabricated epoxy compositesare recycled in the mixture of heat, acid and solvent, which result inthe dissolution of the epoxy matrix. The epoxy is capable dissolutionunder these conditions because the cross-links in the epoxy matrix areacid-labile and undergo a bond cleavage reaction. As a result, thecross-linked epoxy is transformed into individual epoxy polymers (i.e.,an epoxy thermoplastic), which are soluble in organic solvents. Once theepoxy matrix has sufficiently dissolved into solution, the fibers can beremoved from the solution. The polymeric decomposition products of theepoxy resin can be recovered from the recycling solution vianeutralization with alkali, precipitation, solid-liquid separation toyield epoxy polymer material.

In particular, the present invention relates to the use of reworkableepoxy compositions for the fabrication of recyclable fiber reinforcedepoxy composite, and the recycling of said composites, which includesthe following 3 steps:

STEP 1: THE PREPERATION OF REWORKABLE EPDXY COMPOSITIONS DERIVED FROMEPDXY RESINS AND DEGRADABLE CURING AGENTS

Preferred degradable curing agents are those that contain acid liablegroups that enable the curative to decompose under acidic conditions.Most preferred are polyamine-based degradable hardeners such asaminoacetal, aminoformals hardeners. The preferred series of degradablecuring agents can be used in combination with a variety of diepoxideresin well known in the art. The preferred series of degradable curingagents can be formulated with common additives such as viscositymodifiers, diluents, thixotropic agents, fillers, UV-stabilizers,pigments, adducts to decrease cure time, optical brighteners, adhesionpromoters, accelerators, and other common additives well known in theart to customize the processing properties and/or the final propertiesof the reworkable epoxy composition.

The preferred series of degradable curing agents are represented by thefollowing formula I:

wherein R¹ is hydrogen, alkyl, cycloalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, aryl, heteroaryl, alkoxyalkyl or alkynyl; A is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, thiocarbonyl; B is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene , alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, thiocarbonyl; R² ishydrogen, alkyl, aminoalkyl, alkyl-amino-alkyl, cycloalkyl,heterocycloalkyl, alkenyl, aryl, or heteroaryl; and R³ is hydrogen,alkyl, aminoalkyl, alkyl-amino-alkyl, cycloalkyl, heterocycloalkyl,alkenyl, aryl, or heteroaryl.

In formula I, R¹ is preferably hydrogen, C₁₋₁₂ alkyl, C₃₋₁₂ cycloalkyl,C₆₋₁₂ aryl or C₃₋₁₁ heteroaryl, more preferably hydrogen, C₁₋₆ alkyl,C₄₋₆ cycloalkyl, C₆₋₁₀ aryl or C₃₋₈ heteroaryl, and most preferablyhydrogen, methyl, ethyl, propyl, 2-propyl, butyl, 2-butyl, or t-butyl.

In formula I, A is preferably C₁₋₈ alkylene, C₂₋₁₂alkylene-hetero-alkylene, C₄-₁₆ alkylene-heterocyclo-alkylene, carbonylor thiocarbonyl, more preferably C₁₋₈ alkylene, C₂₋₈alkylene-hetero-alkylene, or C₄₋₁₀ alkylene-heterocyclo-alkylene, andmost preferably ethylene, propylene.

In formula I, B is preferably C₁₋₈ alkylene, C₂₋₁₂alkylene-hetero-alkylene, C₄-₁₆ alkylene-heterocyclo-alkylene, carbonylor thiocarbonyl, more preferably C₁₋₈ alkylene, C₂₋₈alkylene-hetero-alkylene, or C₄₋₁₀ alkylene-heterocyclo-alkylene, andmost preferably ethylene, propylene.

In formula I, R² is preferably hydrogen, C₁₋₈ alkyl, cycloalkyl,heterocycle, aryl, or heteroaryl, each 4 to 10 membered heterocycloalkylcontains at least one ring nitrogen atom and is optionally substitutedat a ring carbon atom with at least one amino group, and most preferablyhydrogen, methyl, or ethyl.

In formula I, R³ is preferably hydrogen, C₁₋₈ alkyl, cycloalkyl,heterocycle, aryl, or heteroaryl, each 4 to 10 membered heterocycloalkylcontains at least one ring nitrogen atom and is optionally substitutedat a ring carbon atom with at least one amino group, and most preferablyhydrogen, methyl, or ethyl.

Preferably, the degradable curing agents of the present invention areselected from the group consisting of:

STEP 2: THE USE OF REWORKABLE EPDXY RESIN COMPOSITIONS FOR THEPREPARATION OF DEGRADABLE FIBER REINFORCED COMPOSITES

The reworkable epoxy compositions in step 1 are combined with glassfibers, carbon fibers, natural fibers, synthetic fibers, or otherfibrous materials in order to prepare reinforced epoxy composites. Thereworkable epoxy compositions in step 1 can also be combined withnon-fibrous reinforcement materials such as nanoparticles, born nitride,carbon nanotubes, carbon black, and other non-fibrous materials in orderto prepare composite materials. The reworkable epoxy compositions havesuitable characteristic that make them amenable for use in standardthermosetting composite manufacturing techniques such as wet lay-up,filament winding, vacuum infusion, compression molding, resin transfermolding.

STEP 3: THE RECYCLING OF A FIBER REINFORCED DEGRADABLE EPDXY RESINCOMPOSITE

The composites fabricated according to step 2 are recycled and materialsrecovered by 1) subjecting the composite material to a recyclingsolution of acid and solvent; 2) subsequent dissolution of the epoxymatrix; 3) removal and recovery of the fibrous materials; 4) recovery ofthe cleaved epoxy matrix via neutralization with alkali andprecipitation by the addition of a non-solvent. The epoxy is capabledissolving under these conditions because the cross-links in the epoxymatrix are acid-labile and undergo a bond cleavage reaction at theacetal, formal moiety of the crosslinking tether. As a result, thecross-linked epoxy is transformed into individual epoxy polymers (i.e.,an epoxy thermoplastic), which are soluble in organic solvents. Both therecovered fibers and the recovered epoxy polymer can be separated,recovered, and may be re-used or re-purposed for other applications. Therecycling solution may contain inorganic or organic acid. Specific butnon-limiting examples of acid suitable for degradation of the epoxymatrix include independently, or in combination, hydrochloric acid,acetic acid, methanesulfonic acid, p-toluene sulfonic acid, nitric acid,sulfuric acid or other acids. The recycling solvent can be almost anycommon solvent, but is most preferably a solvent that is protic innatures. Specific but non-limiting examples include, independently, orin combination, water, methanol, ethanol, ethylene glycol, isopropylalcohol, butyl alcohol, pentanol, hexanol, heptanol, octanol or othercommon alcohols.

Existing thermosetting composite recycling technology entails theincineration of the plastic constitution of the material and recoverythe reinforcement fiber. The use of reworkable epoxy compositions tofabricate composites, as detailed in the present invention, ultimatelyallows a more fully recyclable approach because it enables both plasticand fibers to be recovered from the composite. The details are asfollows:

1. The degradation rate of reinforced degradable epoxy composites underthe recycling conditions can be tuned by the molecular structure of thedegradable curing agent. For example, an epoxy resin composition derivedfrom amino ketal curing agent will degrade more quickly in an acidicsolution than from one derived from an aminoformal curing agent.

2. The cross-linked epoxy resin degrades into epoxy-based polymers,which can be classified as epoxy thermoplastics. The mass recovery ofthis plastic material is high and atom economical as only the acetal,formal moiety is expelled from the original cross-linked material. Epoxythermoplastics are engineered polymers that can be used in otherindustrial applications.

3. The combined mass recovery of the reinforcement materials and epoxydegradation material can exceed 96%, and the reinforcement material canbe recovered in good form provided that is sufficiently stable to theacidic recycling conditions.

4. The recycling method of degradable epoxy resin composites arerelatively mild reaction conditions, economical, and easy to control.

EXAMPLES

Set forth below are examples of the compounds of this invention andmethods of making and using them. They are intended to be illustrativeand not to be constructed as limiting the scope of this invention in anyway.

Example 1: Synthesis of Curing Agent A

N-(2-hydroxyethyl)phthalimide (1000 g), paraformaldehyde (157 g), andp-toluene sulfonic acid (6.8 g) were placed in 1.5 L of toluene in a 5Lround bottom flask equipped with Dean Stark apparatus. After 20 hours atreflux, the reaction was cooled to ambient temperature. Then 2 L ofpetroleum ether (bp: 60-90° C.) was added to the reaction mixture. Thewhite precipitate was collected by filtration and washed with 1 L ofpetroleum ether and dried to yield 950 g of crude protected diamine. Thecrude diamine underwent deprotection by treatment with 3.4 L of 20%aqueous NaOH at reflux. After 10 h at reflux, the reaction mixture wascooled to ambient temperature, extracted with chloroform/isopropanol(3:1). The organic phase dried with anhydrous Na₂SO₄, and then distilledunder vacuum to yield 200 g of curing agent A (Bp=71-72° C. @ 70 Pa): ¹HNMR (CDCl₃, 400 MHz): 4.74 (s, 2H), 3.59 (t, J=5.2 Hz, 4H), 2.89 (t,J=5.2 Hz, 4H).

Example 2: Synthesis of Curing Agent B

N-(2-hydroxyethyl)phthalimide (1000 g), 2,2-dimethoxypropane (280 g),and p-toluene sulfonic acid (8 g) were placed in 1.5 L of toluene in around bottom flask equipped with Dean Stark apparatus. After 20 hours,the reaction was cooled to ambient temperature and then 2 L of petroleumether (bp: 60-90° C.) was added to the reaction mixture. The whiteprecipitate was collected by filtration and washed with 1 L of petroleumether and dried to yield 900 g of crude protected diamine. The crudediamine underwent deprotection by treatment with 80% hydrazine hydrate(460 g) in ethanol (600 mL) at reflux. After 10 h at reflux, thereaction mixture was cooled to ambient temperature and the precipitatewas filtered from the solution and washed with ethanol anddichloromethane, respectively. The organic phases were combined, driedwith is anhydrous Na₂SO₄, and then distilled under vacuum to afford 200g of curing agent B (Bp=61-64° C. @ 80 Pa): ¹H NMR (CDCl₃, 400 MHz):3.47 (t, J=5.2 Hz ,4H), 2.85 (t, J=5.2 Hz, 4H), 1.38 (s, 6H).

Example 3: Preparation of a Reworkable Epoxy Composition and Fabricationof a Carbon Fiber Composite

A reworkable epoxy composition was prepared by blending curing agent A(20 g) and a bisphenol A epoxy resin 828 (112 g, epoxy equivalentweight=185-192) at room temperature. This composition was used tofabricate a carbon fiber reinforced degradable epoxy composite using awet lay-up method. Three pieces of woven carbon fiber fabric (3K) wereused. After a final stage cure (2 h at 80° C., then 1 h at 125° C.), acarbon fiber composite obtained.

Example 4: Preparation of a Reworkable Epoxy Composition and Fabricationof a Carbon Fiber Composite

A reworkable epoxy composition was prepared by blending curing agent B(20 g) and a bisphenol A epoxy resin 828 (93 g, epoxy equivalentweight=185-192) at room temperature. This composition was used tofabricate a carbon fiber reinforced degradable epoxy composite using awet lay-up method. Three pieces of woven carbon fiber fabric (3K) wereused. After a final stage cure (2 h at 80° C., then 1 h at 125° C.), acarbon fiber composite was obtained.

Example 5: Recycling of a Degradable Epoxy Composite

A portion (0.42 g) of the carbon fiber composite prepared in Example 3was added to a stirring, hot (150-155° C.) solution of concentratedhydrochloric acid (10 ml) in ethylene glycol (55 ml). After 4 hours, thecarbon fiber was recovered via hot filtration. The epoxy resindegradation product was recovered by precipitation and filtration afterthe neutralization of the filtrate solution with 20% aqueous NaOH. Themass recovery of the combined fiber and epoxy degradation product wasabove 96%. The surface of the recycled carbon fiber appeared clean withno defects.

Example 6: Recycling of a Degradable Epoxy Composite

A portion (0.5 g) of the carbon fiber composite prepared in Example 4was added to a stirring, hot (150-155° C.) solution of concentratedhydrochloric acid (10 ml) in ethylene glycol (90 ml). After 4 hours, thecarbon fiber was recovered via hot filtration. The epoxy resindegradation product was recovered by precipitation and filtration afterthe neutralization of the filtrate solution with 20% to aqueous NaOH.The mass recovery of the combined fiber and epoxy degradation productwas above 96%. The surface of the recycled carbon fiber appeared cleanwith no defects.

Example 7: Recycling of a Degradable Epoxy Composite

A portion (0.27 g) of the carbon fiber composite prepared in Example 3was added to a stirring, hot (120° C.) solution of concentratedhydrochloric acid (10 ml) in butyl alcohol (90 ml). After 4 hours, thecarbon fiber was recovered via hot filtration. The epoxy resindegradation product was recovered by precipitation and filtration afterthe neutralization of the filtrate solution with 20% aqueous NaOH. Themass recovery of the combined fiber and epoxy degradation product wasabove 96%. The surface of the recycled carbon fiber appeared clean withno defects.

Example 8: Recycling of a Degradable Epoxy Composite

A portion (0.64 g) of the carbon fiber composite prepared in Example 3was added to a stirring, hot (120° C.) solution of concentratedhydrochloric acid (10 ml) in ethylene glycol (90 ml). After 4 hours, thecarbon fiber was recovered via hot filtration. The epoxy resindegradation product was recovered by precipitation and filtration afterthe neutralization of the filtrate solution with 20% aqueous NaOH. Themass recovery of the combined fiber and epoxy degradation product wasabove 96%. The surface of the recycled carbon fiber appeared clean withno defects.

Example 9: Recycling of a Degradable Epoxy Composite

A portion (0.54 g) of the carbon fiber composite prepared in Example 4was added to a stirring, hot (80° C.) solution of acetic acid (20 ml),ethanol (40 ml) and water (40 ml). After 4 hours, the carbon fiber wasrecovered via hot filtration. The epoxy resin degradation product wasrecovered by precipitation and filtration after the neutralization ofthe filtrate solution with 20% aqueous NaOH. The mass recovery of thecombined fiber and epoxy degradation product was above 98%. The surfaceof the recycled carbon fiber appeared clean with no defects.

Example 10: Recycling of a Degradable Epoxy Composite

A portion (0.44 g) of the carbon fiber composite prepared in Example 4was added to a stirring, hot (80° C.) solution of acetic acid (20 ml),ethylene glycol (40 ml) and water (40 ml). After 4 hours, the carbonfiber was recovered via hot filtration. The epoxy resin degradationproduct was recovered by precipitation and filtration after theneutralization of the filtrate solution with 20% aqueous NaOH. The massrecovery of the combined fiber and epoxy degradation product was above98%. The surface of the recycled carbon fiber appeared clean with nodefects.

to Example 11: Recycling of a Degradable Epoxy Composite

A portion (0.3 g) of the carbon fiber composite prepared in Example 4was added to a stirring, hot (80° C.) solution of acetic acid (10 ml),ethanol (50 ml) and water (40 ml). After 4 hours, the carbon fiber wasrecovered via hot filtration. The epoxy resin degradation product wasrecovered by precipitation and filtration after the neutralization ofthe filtrate solution with 20% aqueous NaOH. The mass recovery of thecombined fiber and epoxy degradation product was above 98%. The surfaceof the recycled carbon fiber appeared clean with no defects.

Example 12: Preparation and Demonstration of Recycling of Mobile PhoneCase

A prototype carbon fiber mobile phone case was prepared from areworkable epoxy composition as prepared in example 4, using threepieces of woven carbon fiber fabric (3K) via wet lay-up techniques usinga mobile phone casing mold. The phone case was released from the moldafter a final stage cure (2 h at 80° C., then 1 h at 125° C.). Themobile phone case had a weight of 12.9 g. The composite case wasimmersed in a solution of acetic acid/ethanol/water (50 ml/250 ml/200ml)at 80° C. After 5 hours, the carbon fiber was recovered by hotfiltration. The polymeric epoxy degradation product was recovered viaprecipitation and filtration after the neutralization of the filtratesolution with 20% aqueous NaOH. 7.87 g of carbon fiber was recoveredfrom the recycling. The surface of the carbon fiber appeared clean withno apparent defects. 4.82 g of epoxy degradation byproduct was obtainedas a white solid. The mass recovery of the combined fiber and epoxydegradation product was above 98%. The recovered epoxy degradationproduct was analyzed with GPC using polyethylene oxide standards to givethe following data: Mn=125 KDa; MW=193 KDa; PDI=1.53. The ¹H NMR of theepoxy degradation byproduct was similar to the ¹H NMR obtained from thepolymerization product of ethanolamine and bisphenol A digycidyl ether.

Example 13: Preparation and Demonstration of Recycling of Carbon FiberPlate

A prototype carbon fiber plate was prepared from a reworkable epoxycomposition as prepared in example 3, using two pieces of woven carbonfiber fabric (3K) via vacuum infusion techniques using a plate mold. Theplate was released from the mold after a final stage cure (2 h at 80°C., then 1 h at 125° C.). The plate had a size of 10 cm*8 cm. Thecomposite plate was immersed in a solution of concentrate hydrochlorideacid/ethylene glycol (50 ml/450 ml) at 110-115° C. After 4 hours, thecarbon fiber was recovered by hot filtration. The surface of the carbonfiber appeared clean with no apparent defects.

Example 14: Comparison of Non-Composite Cured Epoxy Properties

Properties of non-composite epoxy system cured with Curing agent A werecompared with properties of non-composite epoxy systems cured with othercuring agent amines (Jeffamine® EDR-148 and D-230). Epoxy compositionswere prepared by blending the curing agent and a bisphenol A epoxy resin828 (epoxy equivalent weight=185-192) at room temperature, then cured (2h at 80° C., then 1 h at 125° C.), and testing was carried out accordingto GB standards. Data have shown that some mechanic properties ofnon-composite epoxy system cured with Curing agent A are comparable withthe mechanic properties of non-composite epoxy systems cured with othercuring agent amines (Jeffamine® EDR-148 and D-230).

The examples described herein also serve to demonstrate the fact thatmolecular structure of the degradable curing agents can be used toultimately tune the degradability characteristics of the reworkableepoxy compositions, and therefore, the degradation properties of theircured composite structures. For example, the composite in example 8 isderived from a reworkable epoxy composition that employs curing agent A,which contains formal linkages. This composite requires more stronglyacidic conditions and higher temperature to readily degrade. On theother hand, as demonstrated by example 9, a composite fabricated from areworkable epoxy composition that employs curing agent B is readilydegradable by employment of more weakly acidic conditions and at lowertemperature. Curing agent B contains ketal linkages, which are morereadily hydrolyzed in acidic conditions relative to the formal linkages.

The invention has been described above with the reference to specificexamples and embodiments, not to be constructed as limiting the scope ofthis invention in any way. It is understood that various modificationsand additions can be made to the specific examples and embodimentsdisclosed without departing from the spirit of the invention, and allsuch modifications and additions are contemplated as being part of thepresent invention.

1. A reinforced composite comprising a reinforcement material in across-linked polymer matrix, wherein the cross-linked polymer comprisesa cross-linking group derived from a curing agent represented by formulaI:

Wherein R¹ is hydrogen, alkyl, cylcoalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, aryl, heteroaryl, alkoxy alkyl, or alkynyl; A is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, or thiocarbonyl; B is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, or thiocarbonyl; R² ishydrogen, alkyl, aminoalkyl, cylcoalkyl, heterocycloalkyl, alkenyl,aryl, or heteroaryl; and R³ is hydrogen, alkyl, aminoalkyl,alkyl-amino-alkyl, cylcoalkyl, heterocycloalkyl, alkenyl, aryl, orheteroaryl.
 2. The reinforced composite according to claim 1, whereinthe cross-linked polymer is a cross-linked epoxy resin.
 3. Thereinforced composite according to claim 2, wherein the epoxy resin is atleast one selected from the group consisting of glycidyl ether epoxyresin, glycidyl ester epoxy resin, glycidyl amine epoxy resin, alicyclicepoxy resin, aliphatic epoxy resin, and phenolic epoxy resin.
 4. Thereinforced composite according to claim 1, wherein the reinforcementmaterial is a fibrous material or a non-fibrous material.
 5. Thereinforced cornposite according to claim 4, wherein the fibrous materialis at least one selected from the group consisting of glass fiber,carbon fiber, natural fiber, and chemical fiber; and the non-fibrousmaterial is at least one selected from a the group consisting of carbonnanotube, carbon black, metal nanoparticle, organic nanoparticle, ironoxide, and boron nitride.
 6. The reinforced composite according to claim1, wherein the cross-linked polymer matrix is derived from a degradablecuring agent, an epoxy resin and an optional auxiliary material, and thecuring agent is represented by the following formula I:

wherein R¹ is hydrogen, alkyl, cylcoalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, aryl, heteroaryl, alkoxy alkyl, or alkynyl; A is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, or thiocarbonyl; B is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, or thiocarbonyl; R² ishydrogen, alkyl, aminoalkyl, cylcoalkyl, heterocycloalkyl, alkenyl,aryl, or heteroaryl; and R³ is hydrogen, alkyl, aminoalkyl,alkyl-amino-alkyl, cylcoalkyi, heterocycloalkyl, alkenyl, aryl, orheteroaryl.
 7. The reinforced composite according to claim 6, whereinthe auxiliary material is at least one selected from the groupconsisting of accelerator, diluents, toughening agent, thickening agent,adhesion promoter, optical brightener, pigment, adducting component,coupling agent, filler, decorative component, thixotropic agent,fluorophore, UV-absorber, anti-oxidant, and gloss additive.
 8. Thereinforced composite according to claim 1, wherein the reinforcedcomposite is prepared by at least one method selected from the groupconsisting of wet lay-up, vacuum infusion, filament winding, and resintransfer molding.
 9. A method for recycling the reinforced compositeaccording to claim 1, comprising a step of degrading the cross-linkedpolymer matrix using an add and a solvent.
 10. The method according toclaim 9, wherein the degrading is performed under a heating condition.11. The method according to claim 9, wherein the acid is at least oneselected from the group consisting of hydrochloric acid, acetic acid,lactic acid, formic acid, propionic acid, citric acid, methane sulfonicacid, p-toluene sulfonic acid, nitric acid, sulfuric acid, benzoic acid,and phthalic acid.
 12. The method according to claim 9, wherein thesolvent is at least one selected from the group consisting of methanol,ethanol, ethylene glycol, isopropyl alcohol, butyl alcohol, pentanol,hexanol, heptanol, octanol alcohol, nonyl alcohol, and water.
 13. Themethod according to claim 9, wherein the acid has a concentration in arange of 2-90% by weight, preferably 10-20% by weight.
 14. The methodaccording to claim 10, wherein the heating temperature is 15-400° C.,preferably 80-120° C., and the heating time is 1-24 hours, preferably4-8 hours.
 15. The method according to claim 9, further comprising astep of recovering the degradation product via a filtration processand/or a precipitation process.
 16. The method according to claim 9.wherein the cross-linked polymer is cross-linked epoxy resin.
 17. NewThe method according to claim 16, wherein the epoxy resin is at leastone selected from the group consisting of glycidyl ether epoxy resin,glycidyl ester epoxy resin, glycidyl amine epoxy resin, alicyclic epoxyresin, aliphatic epoxy resin, and phenolic epoxy resin.
 18. The methodaccording to claim 9, wherein the epoxy resin is a fibrous materialselected from the group consisting of glass fiber, carbon fiber, naturalfiber, and chemical fiber; or the epoxy resin is a non-fibrous materialselected from the group consisting of carbon nanotube, carbon black,metal nanoparticle, organic nanoparticle, iron oxide, and boron nitride.19. The method according to claim 9, wherein the cross-linked polymermatrix is derived from a degradable curing agent, an epoxy resin and anoptional auxiliary material, and the curing agent is represented by thefollowing formula I:

wherein R¹ is hydrogen, alkyl, cylcoalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, aryl, heteroaryl, alkoxy alkyl, or alkynyl; A is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, or thiocarbonyl; B is alkyl,alkenyl, alkenene, alkylene-hetero-alkylene,alkylene-heterocyclo-alkylene, alkylene, alkylene-oxy-alkylene,1,4-alkyl substituted piperazine, carbonyl, or thiocarbonyl; R² ishydrogen, alkyl, arninoalkyl, alkyl-amino-alkyl, cylcoalkyl,heterocycloalkyl, alkenyl, aryl, or heteroaryl; and R³ is hydrogen,alkyl, aminoalkyl, alkyl-amino-alkyl, cylcoalkyl, heterocycloalkyl,alkenyl, aryl, or heteroaryl.
 20. The method according to claim 19,wherein the auxiliary material is at least one selected from the groupconsisting of accelerator, diluents, toughening agent, thickening agent,adhesion promoter, optical brightener, pigment, adducting component,coupling agent, filler, decorative component, thixotropic agent,fluorophore, UV-absorber, anti-oxidant, and gloss additive.